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Two particle cluster calculation of the chemical spinodal

Author

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  • Van Der Haegen, R.
  • Luyckx, R.
  • Lekkerkerker, H.N.W.

Abstract

The spinodal curve for demixing in a binary mixture is calculated in the two-particle cluster approximation. It is found that the difference between the equilibrium composition xe and the spinodal composition xs is smaller than in the mean-field approximation. The results agree remarkably well with the semi-empirical formula for the metastable region proposed by Cook and Hilliard (Trans. Met. Soc. AIME 233 (1965) 142).

Suggested Citation

  • Van Der Haegen, R. & Luyckx, R. & Lekkerkerker, H.N.W., 1981. "Two particle cluster calculation of the chemical spinodal," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 107(3), pages 622-628.
    • Handle: RePEc:eee:phsmap:v:107:y:1981:i:3:p:622-628
    DOI: 10.1016/0378-4371(81)90193-X
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    References listed on IDEAS

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    1. Storing, Herbert J. & Strauss, Leo & Berns, Walter & Storing, Herbert J. & Weinstein, Leo & Horwitz, Robert, 1963. "Replies to Schaar and Wolin: I," American Political Science Review, Cambridge University Press, vol. 57(1), pages 151-160, March.
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