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Nanoengineering of MgSO4 nanohybrid on MXene substrate for efficient thermochemical heat storage material

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  • Ur Rehman, Ata
  • Zhao, Tianyu
  • Shah, Muhammad Zahir
  • Khan, Yaqoob
  • Hayat, Asif
  • Dang, Changwei
  • Zheng, Maosheng
  • Yun, Sining

Abstract

2D MXene nanohybrid is a next-generationenergy-storage material. Here, we demonstrate a novel thermochemical heat storage material using magnesium sulfate heptahydrate/titanium carbide and MXene (MgSO4/Ti3C2Tx) with improved hydration/dehydration enthalpy, superior thermal conductivity, good cyclic ability, maximum water sorption performance, and larger thermal energy conversion. The TG-DSC fitted with a Wetsys flow humidity generator shows outstanding thermal performance and larger hydration for MgSO4/Ti3C2Tx (1963 J/g) and dehydration (1861 J/g) enthalpies with 5 % fluctuation as compared to pure MgSO4 (38 %). The cyclicability results showed that MgSO4/MXene has good stability of TCMs across several charging/discharging cycles (up to 20 cycles), confirming that the MXene matrix avoids hydrated salt agglomeration and displays an average of 12 % fluctuation. This illustrates that prepared composites potentially improve storage performance. The MgSO4/Ti3C2Tx nanohybrid exhibit a better radiation absorption and 45 % longer backup than the pristine MgSO4 salt. TEM study revealedthat maximum salt contents can be located in the interlayer gaps, predicted sheets thickness of the MgSO4/MXene layer to be 16 Åand the Ti3C2Tx layers to be 7.3 Å. Nanohybrid has stronger water sorption than MgSO4 due to MXene nanosheets larger interlayer gaps. The results conclude that the resultant MgSO4/MXene has excellent long-term thermal energy storage, photo-to-thermal conversion and larger water sorption performance. The study validates the effectiveness of nanohybrid material as a promising candidate for thermochemical heat storage applications and set to pave the way to explore other hybrid systems to improve the efficiency of thermochemical energy storage systems.

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  • Ur Rehman, Ata & Zhao, Tianyu & Shah, Muhammad Zahir & Khan, Yaqoob & Hayat, Asif & Dang, Changwei & Zheng, Maosheng & Yun, Sining, 2023. "Nanoengineering of MgSO4 nanohybrid on MXene substrate for efficient thermochemical heat storage material," Applied Energy, Elsevier, vol. 332(C).
    • Handle: RePEc:eee:appene:v:332:y:2023:i:c:s0306261922018062
    DOI: 10.1016/j.apenergy.2022.120549
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    1. Barreneche, Camila & Fernández, Ana Inés & Cabeza, Luisa F. & Cuypers, Ruud, 2015. "Thermophysical characterization and thermal cycling stability of two TCM: CaCl2 and zeolite," Applied Energy, Elsevier, vol. 137(C), pages 726-730.
    2. Weiqian Tian & Armin VahidMohammadi & Zhen Wang & Liangqi Ouyang & Majid Beidaghi & Mahiar M. Hamedi, 2019. "Layer-by-layer self-assembly of pillared two-dimensional multilayers," Nature Communications, Nature, vol. 10(1), pages 1-10, December.
    3. Dai, Hancheng & Mischke, Peggy & Xie, Xuxuan & Xie, Yang & Masui, Toshihiko, 2016. "Closing the gap? Top-down versus bottom-up projections of China’s regional energy use and CO2 emissions," Applied Energy, Elsevier, vol. 162(C), pages 1355-1373.
    4. Stella P. Jesumathy & M. Udayakumar & S. Suresh, 2012. "Thermal characteristics in latent heat energy storage system using paraffin wax," International Journal of Energy Technology and Policy, Inderscience Enterprises Ltd, vol. 8(1), pages 50-64.
    5. Pereira da Cunha, Jose & Eames, Philip, 2016. "Thermal energy storage for low and medium temperature applications using phase change materials – A review," Applied Energy, Elsevier, vol. 177(C), pages 227-238.
    6. Michel, Benoit & Mazet, Nathalie & Neveu, Pierre, 2016. "Experimental investigation of an open thermochemical process operating with a hydrate salt for thermal storage of solar energy: Local reactive bed evolution," Applied Energy, Elsevier, vol. 180(C), pages 234-244.
    7. Agyenim, Francis & Hewitt, Neil & Eames, Philip & Smyth, Mervyn, 2010. "A review of materials, heat transfer and phase change problem formulation for latent heat thermal energy storage systems (LHTESS)," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(2), pages 615-628, February.
    8. Yang, Haiyue & Wang, Yazhou & Yu, Qianqian & Cao, Guoliang & Yang, Rue & Ke, Jiaona & Di, Xin & Liu, Feng & Zhang, Wenbo & Wang, Chengyu, 2018. "Composite phase change materials with good reversible thermochromic ability in delignified wood substrate for thermal energy storage," Applied Energy, Elsevier, vol. 212(C), pages 455-464.
    9. Abbas, Yasir & Yun, Sining & Wang, Ziqi & Zhang, Yongwei & Zhang, Xianmei & Wang, Kaijun, 2021. "Recent advances in bio-based carbon materials for anaerobic digestion: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 135(C).
    10. Kant, K. & Pitchumani, R., 2022. "Advances and opportunities in thermochemical heat storage systems for buildings applications," Applied Energy, Elsevier, vol. 321(C).
    11. Jankowski, Nicholas R. & McCluskey, F. Patrick, 2014. "A review of phase change materials for vehicle component thermal buffering," Applied Energy, Elsevier, vol. 113(C), pages 1525-1561.
    12. Li, Wei & Klemeš, Jiří Jaromír & Wang, Qiuwang & Zeng, Min, 2022. "Salt hydrate–based gas-solid thermochemical energy storage: Current progress, challenges, and perspectives," Renewable and Sustainable Energy Reviews, Elsevier, vol. 154(C).
    Full references (including those not matched with items on IDEAS)

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    1. Li, Wei & Markides, Christos N. & Zeng, Min & Peng, Jian, 2024. "4E evaluations of salt hydrate-based solar thermochemical heat transformer system used for domestic hot water production," Energy, Elsevier, vol. 286(C).

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