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Experimental analysis and analytical modeling of Enhanced-Ragone plot

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  • Catenaro, Edoardo
  • Rizzo, Denise M.
  • Onori, Simona

Abstract

In this study, we propose an experimentally validated Enhanced-Ragone plot (ERp) that displays key characteristics of lithium-ion batteries (LIBs) in terms of their cathode composition and operating conditions, and can be employed as a design tool to guide energy storage system (ESS) selection for applications ranging from electrified vehicles to stationary grid storage. We build the ERp using experiments - under different C-rate and operating temperature - from cylindrical graphite anode LIBs of the type 1865 nickel-cobalt-aluminum-oxide, 2170 nickel-manganese-cobalt-oxide and 2665 iron-phosphate. Moreover, for each LIB tested, six cell samples are used to assess the statistical significance and repeatability of the data collected. A zero-th order equivalent circuit-based modeling approach is then proposed and experimentally validated to predict the specific energy and specific power on the ERp. Finally, the proposed ERp framework is showed on a case study of battery sizing in electric vehicle applications.

Suggested Citation

  • Catenaro, Edoardo & Rizzo, Denise M. & Onori, Simona, 2021. "Experimental analysis and analytical modeling of Enhanced-Ragone plot," Applied Energy, Elsevier, vol. 291(C).
  • Handle: RePEc:eee:appene:v:291:y:2021:i:c:s0306261921000386
    DOI: 10.1016/j.apenergy.2021.116473
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    References listed on IDEAS

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    1. Zhang, Yuan Ci & Briat, Olivier & Boulon, Loïc & Deletage, Jean-Yves & Martin, Cyril & Coccetti, Fabio & Vinassa, Jean-Michel, 2019. "Non-isothermal Ragone plots of Li-ion cells from datasheet and galvanostatic discharge tests," Applied Energy, Elsevier, vol. 247(C), pages 703-715.
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    Cited by:

    1. Dettù, Federico & Pozzato, Gabriele & Rizzo, Denise M. & Onori, Simona, 2021. "Exergy-based modeling framework for hybrid and electric ground vehicles," Applied Energy, Elsevier, vol. 300(C).
    2. Catenaro, Edoardo & Rizzo, Denise M. & Onori, Simona, 2021. "Framework for energy storage selection to design the next generation of electrified military vehicles," Energy, Elsevier, vol. 231(C).

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