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Effect of CO2 partial pressure on dry reforming of ethanol for hydrogen production

Author

Listed:
  • Fahim Fayaz
  • Ahmad Ziad Sulaiman
  • Sharanjit Singh
  • Sweeta Akbari

Abstract

The effect of CO2 partial pressure on ethanol dry reforming was evaluated over 5%Ce-10%Co/Al2O3 catalyst at = PCO2 = 20-50 kPa, PC2H5OH = 20 kPa, reaction temperature of 973 K under atmospheric pressure. The catalyst was prepared by using impregnation method and tested in a fixed-bed reactor. X-ray diffraction measurements studied the formation of Co3O4, spinel CoAl2O4 and CeO2, phases on surface of 5%Ce-10%Co/Al2O3 catalyst. CeO2, CoO and Co3O4 oxides were obtained during temperature–programmed calcination. Ce-promoted 10%Co/Al2O3 catalyst possessed high BET surface area of 137.35 m2 g-1. C2H5OH and CO2 conversions was improved with increasing CO2 partial pressure from 20-50 kPa whilst the optimal selectivity of H2 and CO was achieved at 50 kPa.

Suggested Citation

  • Fahim Fayaz & Ahmad Ziad Sulaiman & Sharanjit Singh & Sweeta Akbari, 2018. "Effect of CO2 partial pressure on dry reforming of ethanol for hydrogen production," International Journal of Innovative Research and Scientific Studies, Innovative Research Publishing, vol. 1(1), pages 6-10.
  • Handle: RePEc:aac:ijirss:v:1:y:2018:i:1:p:6-10:id:3
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