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Thermal Cycling Test of Solar Salt in Contact with Sustainable Solid Particles for Concentrating Solar Power (CSP) Plants

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  • Marc Majó

    (Department of Materials Science and Physical Chemistry, Universitat de Barcelona, Martí I Franqués 1-11, 08028 Barcelona, Spain)

  • Adela Svobodova-Sedlackova

    (Department of Materials Science and Physical Chemistry, Universitat de Barcelona, Martí I Franqués 1-11, 08028 Barcelona, Spain)

  • Ana Inés Fernández

    (Department of Materials Science and Physical Chemistry, Universitat de Barcelona, Martí I Franqués 1-11, 08028 Barcelona, Spain)

  • Alejandro Calderón

    (Department of Materials Science and Physical Chemistry, Universitat de Barcelona, Martí I Franqués 1-11, 08028 Barcelona, Spain)

  • Camila Barreneche

    (Department of Materials Science and Physical Chemistry, Universitat de Barcelona, Martí I Franqués 1-11, 08028 Barcelona, Spain)

Abstract

Thermal energy storage (TES) is crucial in bridging the gap between energy demand and supply globally. Concentrated Solar Power (CSP) plants, employing molten salts for thermal storage, stand as an advanced TES technology. However, molten salts have drawbacks like corrosion, solidification at lower temperatures, and high costs. To overcome these limitations, research is focusing on alternative TES materials such as ceramic particles. These solids match molten salts in energy density and can withstand higher temperatures, making them well-suited for CSP systems. This study revolves around subjecting Solar Salt alone and Solar Salt alongside Volcanic Ash (VA) and Electric Arc Furnace Slag (EAFS) to a comprehensive thermal cycling test. This test is designed to assess the compatibility over the thermal cycles of the Solar Salt and the Solar Salt in contact with these solids in a CSP plant with a thermocline configuration. With a final thermal and chemical evaluation, our observations indicate that EAFS and VA demonstrate promising compatibility but an increase in the reduction rate of the Solar Salt due to a catalyst effect from EAFS in contact with the salt. No discernible alterations were detected in the properties of either the solid materials or solar salt when combined.

Suggested Citation

  • Marc Majó & Adela Svobodova-Sedlackova & Ana Inés Fernández & Alejandro Calderón & Camila Barreneche, 2024. "Thermal Cycling Test of Solar Salt in Contact with Sustainable Solid Particles for Concentrating Solar Power (CSP) Plants," Energies, MDPI, vol. 17(10), pages 1-10, May.
    • Handle: RePEc:gam:jeners:v:17:y:2024:i:10:p:2349-:d:1393682
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    References listed on IDEAS

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    1. Bauer, Thomas & Pfleger, Nicole & Breidenbach, Nils & Eck, Markus & Laing, Doerte & Kaesche, Stefanie, 2013. "Material aspects of Solar Salt for sensible heat storage," Applied Energy, Elsevier, vol. 111(C), pages 1114-1119.
    2. Villada, Carolina & Bonk, Alexander & Bauer, Thomas & Bolívar, Francisco, 2018. "High-temperature stability of nitrate/nitrite molten salt mixtures under different atmospheres," Applied Energy, Elsevier, vol. 226(C), pages 107-115.
    3. Gutierrez, Andrea & Miró, Laia & Gil, Antoni & Rodríguez-Aseguinolaza, Javier & Barreneche, Camila & Calvet, Nicolas & Py, Xavier & Inés Fernández, A. & Grágeda, Mario & Ushak, Svetlana & Cabeza, Luis, 2016. "Advances in the valorization of waste and by-product materials as thermal energy storage (TES) materials," Renewable and Sustainable Energy Reviews, Elsevier, vol. 59(C), pages 763-783.
    4. Calderón, Alejandro & Palacios, Anabel & Barreneche, Camila & Segarra, Mercè & Prieto, Cristina & Rodriguez-Sanchez, Alfonso & Fernández, A. Inés, 2018. "High temperature systems using solid particles as TES and HTF material: A review," Applied Energy, Elsevier, vol. 213(C), pages 100-111.
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